化学计量学
偏最小二乘回归
傅里叶变换红外光谱
主成分回归
化学
分析化学(期刊)
校准
过氧化物
过氧化值
主成分分析
色谱法
数学
有机化学
统计
光学
物理
作者
Nur Çebi,Mustafa Tahsin Yılmaz,Osman Sağdıç,Hande YÜCE,Emrah Yelboğa
标识
DOI:10.1016/j.foodchem.2017.01.013
摘要
Our work explored, for the first time, monitoring peroxide value (PV) of omega-3 rich algae oil using ATR-FTIR spectroscopic technique. The PV of the developed method was compared by that obtained by standard method of Association of Official Analytical Chemists (AOAC). In this study, peak area integration (PAI), Partial Least Squares Regression (PLSR), and Principal Component Regression (PCR) were used as the calibration techniques. PV obtained by the AOAC method and by FTIR-ATR technique were well correlated considering the peak area related to trans double bonds and chemometrics techniques of PLSR and PCR. Calibration model was established using the band with a peak point at 966 cm−1 (990–940 cm−1) related to CH out of plane deformation vibration of trans double bond. Algae oil oxidation could be successfully quantified using PAI, PLSR and PCR techniques. Additionally, hierarchical cluster analysis was performed and significant discrimination was observed coherently with oxidation process.
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