玉米芯
木糖醇
催化作用
木聚糖
产量(工程)
化学
金属
化学工程
半纤维素
材料科学
有机化学
木质素
原材料
多糖
发酵
复合材料
工程类
作者
Lucília S. Ribeiro,J.J.M. Órfão,M. Fernando R. Pereira
标识
DOI:10.1515/gps-2016-0174
摘要
Abstract Different supported metal catalysts were tested for the one-pot transformation of corncob xylan to xylitol. The influence of several factors, such as catalytic support, nature of metal, metal loading, amount of catalyst, hydrogen pressure and reaction temperature, was investigated. The results revealed that xylan can be converted into xylitol with a yield close to 80% after 2 h of reaction using Ru supported on carbon nanotubes (CNT, 0.4 wt% metal loading) with excellent stability after repeated use, at a temperature of 170°C and an H 2 pressure of 50 bar. The yield of xylitol achieved is one of the highest ever reported for the direct conversion of xylan to xylitol using an environmentally friendly process.
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