磷光
材料科学
红外线的
荧光
能量转移
放射化学
化学
原子物理学
物理
光学
作者
Huimin Li,Ran Pang,Su Zhang,Lingling Lv,Jing Feng,Lihong Jiang,Da Li,Chengyu Li,Hongjie Zhang
出处
期刊:Dalton Transactions
[The Royal Society of Chemistry]
日期:2018-01-01
卷期号:47 (29): 9814-9823
被引量:9
摘要
Near-infrared (NIR) long-lasting phosphorescence (LLP) phosphors have potential applications in biological and military fields. However, the properties of these phosphors are insufficient to satisfy the demands. Herein, we report a series of novel LLP phosphors Zn1.98-xLi0.02P2O7:xYb3+ with strong NIR LLP. By investigating the O-Yb3+ charge transfer (CT) band and host thoroughly, it can be confirmed that distinct photoluminescence (PL) of the two can be realized by selecting an appropriate excitation. For NIR emission, considering that the emission of Yb3+ originates from the characteristic 4f-4f transition between 4F5/2 and 4F7/2 levels and the difference between these two levels is too small to be excited by UV light, it is practicable to use the energy transfer of the host rather than that of the O-Yb3+ CT band as its energy level does not match with that of Yb3+. LLP is different from PL of the O-Yb3+ CT band, host or Yb3+, and it is strongly dependent on the appropriate depths of the traps; therefore, the selection and regulation of the traps are crucial. Considering the practicability and the demand of NIR LLP materials, we focus on how to excite Yb3+ and obtain LLP.
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