结晶学
粘结长度
分子几何学
化学
Atom(片上系统)
锡
立体化学
物理
晶体结构
分子
计算机科学
嵌入式系统
有机化学
作者
Reza Reisi,Shahirin Siti Munirah,Misni Misran,Kong Mun Lo,Seik Weng Ng
标识
DOI:10.1107/s1600536808023787
摘要
In the centrosymmetric tetranuclear title compound, [Sn4(C4H9)8(C7H5O3)4O2], one of the two independent Sn atoms is five-coordinate in a cis-C2SnO3 trigonal-bipyramidal geometry [C—Sn—C = 142.7 (1)°]; the geometry is distorted owing to a long Sn⋯O(double bond) interaction [Sn⋯O = 2.862 (1) Å]. The other Sn atom has a bent R2Sn skeleton [C—Sn—C = 144.0 (1)°], but the geometry is best regarded as being a trans-C2SnO4 octahedron as the Sn–O(single bond) interaction is shorter [Sn—O = 2.674 (1) Å].
科研通智能强力驱动
Strongly Powered by AbleSci AI