超级电容器
材料科学
电容
石墨烯
电解质
电极
异质结
功率密度
光电子学
纳米技术
氧化物
化学工程
功率(物理)
化学
量子力学
物理
工程类
物理化学
冶金
作者
Yongqi Xu,Bingyige Pan,Weishi Li,Lei Dong,Xinping Wang,Fenglan Zhao
标识
DOI:10.1021/acsami.1c08406
摘要
The energy density formula illuminated that widening the voltage window and maximizing capacitance are effective strategies to boost the energy density of supercapacitors. However, aqueous electrolyte-based devices generally afford a voltage window less than 1.2 V in view of water electrolysis, and chemically converted graphene yields mediocre capacitance. Herein, multi-electron redox-reversible, structurally stable indanthrone (IDT) π-backbones were rationally coupled with the reduced graphene oxide (rGO) framework to form IDT@rGO molecular heterojunctions. Such conductive agent- and binder-free film electrodes delivered a maximized capacitance of up to 345 F g–1 in a potential range of −0.2 to 1.0 V. The partner film electrode–Ti3C2Tx MXene which worked in the negative potential range of −0.1 to −0.6 V–afforded a capacitance as large as 769 F g–1. Thanks to the perfect complementary potentials of the IDT@rGO heterojunction positive electrode and Ti3C2Tx MXene negative partner, the polyvinyl alcohol/H2SO4 hydrogel electrolyte-based flexible asymmetric supercapacitor delivered an enlarged voltage window of 1.6 V and an impressive energy density of 17 W h kg–1 at a high power density of 8 kW kg–1, plus remarkable rate capability and cycling life (capacitance retention of ∼90% after 10000 cycles) as well as exceptional flexibility and bendability.
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