化学
铌
电化学
介电谱
钒
兴奋剂
电极
无机化学
电导率
钠
动力学
钛
扩散
离子
物理化学
材料科学
有机化学
光电子学
热力学
物理
量子力学
作者
William G. Morais,Marina Leite,Roberto M. Torresi
标识
DOI:10.1016/j.jelechem.2021.115595
摘要
Sodium fluorophosphates are among the most promising materials for positive electrodes in sodium-ion batteries; however, their low electronic conductivity, kinetics limitations, and structural instability prevent them from reaching their full potential. We obtained sodium vanadium fluorophosphates (NVPF) doped with Ti4+ (NVTPF) and Nb5+ (NVNPF) via an original low-temperature synthesis. It was observed that Ti4+ doping facilitated access to electrode sites and provided higher capacities at high current densities while Nb5+ provided a 91.7% capacity retention from the 20th to 200th cycle, which was over the 80.1% capacity retention of NVPF. Moreover, both NVTPF and NVNPF provided diffusion coefficients in the range of ~10−10 cm2 s−1, which was better than ~10−12 cm2 s−1 of NVPF. Additionally, electrochemical impedance spectroscopy and ex situ X-ray diffraction measurements confirmed that Ti4+ enhanced the electrode kinetics and stabilized its structure through sodiation/desodiation reactions. The results presented in this paper might provide insights and new directions to enhance the electrochemical storage properties of fluorophosphates.
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