材料科学
因科镍合金
高温合金
氧化物
尖晶石
动力学
内氧化
金红石
冶金
图层(电子)
化学工程
微观结构
复合材料
合金
物理
量子力学
工程类
作者
G.K. Sujan,Zengxi Pan,Huijun Li,Daniel Liang,Nazmul Alam
标识
DOI:10.1080/02670836.2021.1904614
摘要
This work investigated the high-temperature oxidation kinetics and evolution of oxide phases of as-fabricated (AF) and heat-treated (HT) Inconel 718 alloys in air fabricated by the wire-arc additive manufacturing process. The results showed that the oxidation kinetics of all samples followed the parabolic time dependence. The microstructural study revealed the formation of very similar oxide scales in both AF and HT conditions. The oxide surface was found to be a mixture of complex spinel-MnCr 2 O 4 and rutile-TiO 2 phases. The cross-sectional view yielded an outer layer of protective Cr 2 O 3 scale, an inner layer of Nb-rich Ti 0.67 Nb 1.33 O 4 oxide and discretely formed internal Al 2 O 3 oxides. The mechanism of scale formation is suggested on the basis of thermodynamic and kinetic abilities of cationic species.
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