硝基甲烷
碱金属
溶解度
化学
溶剂
盐(化学)
无机化学
核化学
色谱法
有机化学
作者
Kurt Torssell,Kurt V. Gothelf,Vincent N. G. Lindsay
标识
DOI:10.1002/047084289x.rn041.pub2
摘要
[75-52-5] CH3NO2 (MW 61.05) InChI = 1S/CH3NO2/c1-2(3)4/h1H3 InChIKey = LYGJENNIWJXYER-UHFFFAOYSA-N (building block in synthesis; polar solvent) Physical Data: mp −28.5 °C; bp 101 °C; d 1.13 g cm−3; dipole moment 3.5 D. Solubility: completely misc most organic solvents; slightly sol petroleum ether, water; sol alkaline solution. Form Supplied in: colorless liquid, widely available. Purification: purified by drying over MgSO4 and distilling; a small acidic forerun is discarded. Handling, Storage, and Precautions: stable compound. It is advised not to distill large quantities at reduced pressure. Flammable; toxic. Gives shock- and heat-sensitive alkali and heavy metal salts. Do not dry the sodium salt.
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