化学
试剂
催化作用
组合化学
有机合成
有机化学
作者
G. Santosh,Samata E. Shetgaonkar,Fateh V. Singh
出处
期刊:Current Organic Synthesis
[Bentham Science]
日期:2022-05-01
卷期号:19 (3): 393-413
被引量:14
标识
DOI:10.2174/1570179419666220211102602
摘要
Organoselenium chemistry has developed as an important tool in the field of synthetic and medicinal chemistry. Various organoselenium reagents have been developed and used successfully to achieve different organic transformations such as the selenocyclizations, oxyselenenylations and selenoxide eliminations etc. Additionally, the potential of organoselenium reagents is not limited their use as stoichiometric reagents but they have successfully used as organocatalyst in number of synthetic transformations. Various organic and inorganic oxidants have been identified as terminal oxidants to regenerate the active catalytic specie. In this review article, the recent progress of organoselenium reagents in catalysis is being highlighted along with their asymmetric variants.
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