Secure key distribution is one of the most crucial issues for the security of communication systems. However, it is extremely challenging to realize the gigabit key distribution required for high-speed secure communication. Targeting high-speed secure key distribution, we propose a novel scheme based on chaos synchronization and optical frequency comb technology. By the multi-channel multiplexing, final security key rate is greatly extended to gigabit. The feasibility and performance of the proposed high-speed secure key distribution scheme are verified by numerical simulations.