Anode‐Free Zinc–Bromine Batteries Enabled by a Simple Prenucleation Strategy

Abstract The design of anode‐free zinc (Zn) batteries with high reversibility at high areal capacity has received significant attention recently, which is quietly challenging yet. Here, a Zn alloyed interface through electroplating is introduced, providing homogeneous Zn prenucleation sites to stabilize subsequent Zn nucleation and plating. By employing Zn–Cu alloy as a module, the complementary simulations and characterizations confirm that the prenucleation alloyed interfaces achieve a homogeneous electric field distribution and greatly enhance the stability of the Zn anode. Accordingly, the Zn//Zn–Cu@Cu half‐cells show a long cycle life of over 900 h and an average Coulombic efficiency (CE) of 99.8% at an areal capacity of 10 mAh cm −2 . The assembled anode‐free zinc–bromine (Zn–Br 2 ) battery exhibits an attractive stable cycling of 11 000 cycles at 1 mAh cm −2 , while over 1000 cycles at the higher areal capacity of 10 mAh cm −2 . Excitingly, the Zn–Br 2 pouch cell with a capacity of 1000 mAh operates stably over 50 cycles, and achieves successful integration with photovoltaic systems. This anode‐free Zn–Br 2 batteries constructed through a prenucleation strategy offer new insights into the potential for large‐scale energy storage applications.