Broadband Emission Origin in Metal Halide Perovskites: Are Self‐Trapped Excitons or Ions?

Abstract It has always been a goal to realize high efficiency and broadband emission in single‐component materials. The appearance of metal halide perovskites makes it possible. Their soft lattice characteristics and significant electron–phonon coupling synergistically generate self‐trapped excitons (STEs), contributing to a broadband emission with a large Stokes shift. Meanwhile, their structural/compositional diversity provides suitable active sites and coordination environments for doping of ns 2 ions, allowing 3 P n ( n =0,1,2) → 1 S 0 transitions toward broadband emission. The ns 2 ions emission is phenomenologically similar to that of STE emission, hindering in‐depth understanding of their emission origin, and leading to failure to meet the design requirements for practical applications. In this scenario, herein, the fundamentals and development of such two emission mechanisms are summarized to establish a clear and comprehensive understanding of the broadband emission phenomenon, which may pave the way to an ideal customization of broadband‐emission metal halide perovskites.