Organic Mechanochromic Luminescent Materials with Self‐Recovering Characters

Recently, applied research on stimuli‐responsive materials with luminescence‐switching characteristics has been conducted in various fields. A representative phenomenon of stimuli‐responsive luminescent materials is mechanochromic luminescence (MCL), which exhibits luminescent color change induced by mechanical stimuli such as grinding. These materials are among the most prominent candidates for security and sensing applications. Interestingly, some mechanochromic luminescent materials have shown self‐recovery character, in which their original luminescent color can be recovered by just standing under ambient conditions after grinding. Although there are more and more reports of such materials in recent years, the fundamental principles of molecular design still remain elusive. In this concept, we summarize distinctive advances in mechanochromic luminescent materials with self‐recovery according to the core structures of luminescent molecules. Controlling amorphous state by introducing substituents such as alkyl or polar groups is effective method to provide self‐recovering properties.