Metallic-Bonded Pt–Co for Atomically Dispersed Pt in the Co4N Matrix as an Efficient Electrocatalyst for Hydrogen Generation

Exploiting highly efficient electrocatalysts toward hydrogen evolution reaction (HER) has a significant role in the mass production of hydrogen energy through water electrolysis. Herein, ginkgo leaf-like Co₄N coupled with trace Pt with metallic bond Pt-Co on nickel foam via solvothermal, tannic acid treated, and nitridation procedures for HER (T-Pt-Co₄N) is developed. It only requires low overpotentials of 31 mV and 27 mV to achieve 10 mA cm^-2 in alkaline and neutral electrolytes, respectively, surpassing the benchmark Pt/C and previously reported values. Moreover, it presents excellent long-term stability in the studied media and also can drive overall water splitting under the assistance of sustainable energies. The specific nanostructure favors the acceleration of the electrocatalytic process by exposing abundant active sites and providing numerous mass transport channels during the catalytic process. Moreover, experimental and theoretical calculation demonstrate that the atomic Pt coordinates with Co to form metallic bond Pt-Co also act as crucial role to boost the electrocatalytic performance by optimizing the reaction kinetics for HER.