Stabilizing the Bulk‐Phase and Solid Electrolyte Interphase of Silicon Microparticle Anode by Constructing Gradient‐Hierarchically Ordered Conductive Networks

with µSi-MTCNF-PAA, exhibits a capacity retention rate of 92.0% following 50 cycles. This GHOC network structure can offer an efficacious pathway for stabilizing both the bulk-phase and interphase structure of anode materials with high volumetric strain.