High‐Performance Ceramic Catalyst Filters with Textured Waveguides for Efficient Removal of Volatile Organic Compounds

Abstract The cordierite‐based ceramic catalyst filter (CCF) has attracted considerable attention as a promising future air purification system due to its ability to filtrate particulate matter (PM), as well as decompose volatile organic compounds (VOCs) through ultraviolet (UV)‐activated photocatalytic reactions. Its performance, however, is strictly limited because majority of UV photons are absorbed near the entrance of the high‐aspect‐ratio air‐flow channels, thus, only a limited portion of photocatalysts is activated during the flow of polluted air. In this study, a high‐performance CCF is presented featuring textured waveguides (TWs) aligned with an array of UV light‐emitting diodes (LEDs) emitting at a peak wavelength of 365 nm, which are inserted into an array of high‐aspect‐ratio channels. TWs ensure the delivery of UV photons deep inside channels via total internal reflection and scattering, enabling the activation of majority of photocatalysts, resulting in remarkable improvement in VOCs removal efficiency. The proposed CCF system exhibits much higher formaldehyde (HCHO) removal efficiency by 70% compared to conventional CCF systems even subjected to much lower UV light power densities. It is strongly believed that it is possible to further improve the removal efficiency, while maintaining effective PM filtering and ultralow electrical power consumption, by optimization of the geometry of the CCF system with TWs.