Wedelia chinensis-derived biomass porous carbon as anode material for high performance sodium/potassium-ion batteries

阳极 材料科学 多孔性 生物量(生态学) 碳纤维 电化学 离子 化学工程 化学 复合材料 冶金 电极 农学 复合数 有机化学 生物 物理化学 工程类
作者
Zengwei Pang,Letong Wang,Shenteng Wan,Miaomiao Liu,Xiaohui Niu,Yingde Wang,Hongxia Li
出处
期刊:Ionics [Springer Nature]
卷期号:30 (8): 4655-4664 被引量:1
标识
DOI:10.1007/s11581-024-05604-3
摘要

Sodium-ion batteries (SIBs) and potassium-ion batteries (PIBs) are potential alternatives of lithium-ion batteries (LIBs) due to the abundant and cost-effective availability of sodium and potassium resources. Unfortunately, they are difficult to use for large-scale grid energy storage due to the lack of suitable anode materials for sodium/potassium energy storage. Biomass-derived carbon, which is widely available and environmentally friendly, is one of the most promising anode materials for SIBs/PIBs, but the design and regulation of its microstructure is exceptionally complex. By selecting suitable biomass precursors, it is expected that biomass-derived carbon with suitable microstructures can be simply prepared. In this study, Wedelia chinensis were selected as biomass precursors, and biomass-derived carbon materials with large interfacial spacing, suitable pores and high-specific surface area were prepared by a simple one-step pyrolysis method. The material exhibited fast energy storage kinetics when electrochemically tested as an anode and showed different performance advantages in storing sodium/potassium. When tested as an anode for SIBs, it exhibited excellent specific capacity and cycling stability (380.7 mA h g−1 after 500 cycles at 100 mA g−1); When tested as an anode for PIBs, it exhibited excellent rate performance (128.6 mA h g−1 at 10 A g−1).
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