Thermochromic Vanadium Dioxide Nanostructures for Smart Windows and Radiative Cooling

Abstract The pursuit of energy‐saving materials and technologies has garnered significant attention for their pivotal role in mitigating both energy consumption and carbon emissions. In particular, thermochromic windows in buildings offer energy‐saving potential by adjusting the transmittance of solar irradiation in response to temperature changes. Radiative cooling (RC), radiating thermal heat from an object surface to the cold outer space, also offers a potential way for cooling without energy consumption. Accordingly, smart window and RC technologies based on thermochromic materials can play a crucial role in improving energy efficiency and reducing energy consumption in buildings in response to the surrounding temperature. Vanadium dioxide (VO 2 ) is a promising thermochromic material for energy‐saving smart windows and RC due to its reversible metal‐to‐insulator transition, accompanying large changes in its optical properties. This review provides a brief summary of synthesis methods of VO 2 nanostructures based on nanoparticles and thin films. Moreover, this review emphasizes and summarizes modulation strategies focusing on doping, thermal processing, and structure manipulation to improve and regulate the thermochromic and emissivity performance of VO 2 for smart window and RC applications. In last, the challenges and recent advances of VO 2 ‐based smart window and RC applications are briefly presented.