化学
催化作用
药物化学
组合化学
光化学
有机化学
作者
Meifang Tang,Yanyang Bao,Han Zhang,M. Xiao,Bingbing Feng,Zheliang Yuan,Yanan Wang
标识
DOI:10.1002/ejoc.202400346
摘要
Abstract Here we report a mild protocol for benzylic C−H trifluoromethylthiolation using sodium decatungstate (NaDT) as the photocatalyst. Wherein, photoactivated DT abstracted the benzylic hydrogen atom via a radical process. This transformation works well with a slight excess of benzylic substrates or as limiting reagents for better purification. The reaction shows mild conditions and good functional group tolerance. Moreover, the protocol could be applied to gram‐scale synthesis.
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