Nanocomposite Scintillators Loaded With Hafnium Oxide and Phosphorescent Host and Guest for Gamma Spectroscopy

Gamma sensitive plastic scintillators are of critical importance in the fields of nuclear nonproliferation, medical imaging, and high energy physics. However, there is often a trade-off between high light yield and high loading of high-Z components, both of which play an essential role in gamma ray detection. This work takes advantage of triplet exciton harvesting to increase gamma light yield by utilizing 1,3-di(9H-carbazol-9-yl)benzene and 9,9-dimethyl-9H-fluorene as triplet hosts to facilitate Dexter energy transfer to bis[2-(4,6-difluorophenyl)pyridinato-C2,N](picolinato)iridium(III) (FIrPic), a blue light emitting phosphorescent dye. A plastic scintillator containing 20 wt % MF, 10 wt % mCP, and 2 wt % FIrPic has a high gamma light yield of 14 800 Ph/MeV. Incorporating 20–35 wt % hafnium oxide nanoparticles into this organic matrix results in nanocomposites that demonstrate a gamma photopeak energy resolution of 6.4–9.7% at 662 keV while still retaining a high gamma light yield between 8800 and 10 800 Ph/MeV.