化学
对映选择合成
组合化学
立体化学
有机化学
催化作用
作者
Congbin Fan,Jie Wu,Chenxin Wang,Xinyu Wu,Jiapian Huang
出处
期刊:Synthesis
[Georg Thieme Verlag KG]
日期:2024-05-29
卷期号:56 (17): 2648-2654
摘要
Abstract The sulfinyl group, as one of the bioisosteres of carbonyl groups, attracts considerable attention in the field of synthetic chemistry. In particular, the asymmetric construction of chiral sulfinyl compounds and their derivatives remains in the early stages of development. Sulfinyl compounds mainly include sulfoxides, sulfinate esters and sulfinamides, according to the different functional groups connected to the sulfur atom. This Review summarizes the fascinating recent progress made over the past decade on the asymmetric synthesis of enantiopure sulfinyl derivatives. 1 Introduction 2 Asymmetric Synthesis of Chiral Sulfoxides 3 Asymmetric Synthesis of Chiral Sulfinate Esters 4 Asymmetric Synthesis of Chiral Sulfinamides 5 Conclusion and Outlook
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