Enhanced Fill Factor and Efficiency of Ternary Organic Solar Cells by a New Asymmetric Non‐Fullerene Small Molecule Acceptor

Abstract Asymmetric non‐fullerene small molecules acceptor (as‐NF‐SMAs) exhibit greater vitality in photovoltaic materials compared to their symmetric counterparts due to their larger dipole moments and stronger intermolecular interactions, which facilitate exciton dissociation and charge transmission in organic solar cells (OSCs). Here, we introduced a new as‐NF‐SMAs, named IDT‐TNIC, as the third component in ternary organic solar cells (TOSCs). The asymmetric IDT‐TNIC used indacenodithiophene (IDT) as the central core, alkylthio‐thiophene as a unilateral π‐bridge and extended end groups as electron‐withdrawing. Due to the non‐covalent conformational lock (NCL) established between O⋅⋅⋅S and S⋅⋅⋅S, the IDT‐TNIC molecule preserves its coplanar structure effectively. Furthermore, IDT‐TNIC exhibits complementary absorption and excellent compatibility with donor and acceptor materials, as well as optimized ladder energy level arrangement, resulting in a higher and more balanced μ h / μ e value, more homogeneous and suitable phase separation morphology in TOSCs. Thus, the PCE of the TOSCs reached 17 % when the weight ratio of PM6 : Y6 : IDT‐TNIC was 1 : 1.1 : 0.1, and it is noteworthy that when the device area was increased to 1 cm 2 , the PCE could still be maintained at over 14 %. Detailed studies and analysis indicate that IDT‐TNIC has great potential as a third component in OSCs and for large‐scale printing in the future.