达布科
激进的
化学
催化作用
分子间力
组合化学
有机化学
分子
作者
Xin Yuan,Jie Liu,Hao Lv,Long‐Zhou Qin,Xiu Duan,Jian Wang,Meng‐Yu Wu,Beining Chen,Jiang‐Kai Qiu,Kai Guo
标识
DOI:10.1016/j.gresc.2023.03.002
摘要
Photocatalyzed alkylsulfonylation of unactivated alkenes using DABCO. (SO2)2 and thianthrenium salts via a distal heteroaryl migration process has been developed, which provides a new means of synthesizing a variety of valuable alkylsulfonyl-substituted compounds. These alkylsulfonyl radicals couple with unactivated alkenes to undergo efficient intermolecular reactions, followed by distal heteroaryl migration. This mild catalytic method is tolerant of functional groups and affords medicinally relevant alkylsulfonylated heterocycles.
科研通智能强力驱动
Strongly Powered by AbleSci AI