氧化还原
催化作用
尿素
化学
原位
X射线光电子能谱
拉曼光谱
金属
无机化学
化学工程
有机化学
物理
光学
工程类
作者
Xiaodong Yan,Xiang Li,Wenda Zhang,Hanwen Xu,Yang Yao,Jiangyong Liu,Zhi‐Guo Gu
标识
DOI:10.1016/j.jcis.2022.08.155
摘要
NiOOH has been considered as the active center for urea oxidation reaction (UOR), but it remains challenging to synthesize high-performance NiOOH-based catalysts. Herein, we realize the synthesis of a high-performance NiOOH-based catalyst through in-situ transformation from the NiMn-based metal-organic framework to NiMnOOH. X-ray photoelectron spectroscopy characterization shows that the Ni3+/Ni2+ ratio in the NiMnOOH is 3.9 times as big as that in the Ni(OH)2, and in-situ Raman characterization further consolidates the presence of the NiOOH species in the NiMnOOH and as well unveils the faciliated Ni2+/Ni3+ redox reaction. The abundant NiOOH species, the markedly facilitated Ni2+/Ni3+ redox reaction and the Ni-Mn synergy contribute to the high intrinsic activity of the NiMnOOH towards UOR. The NiMnOOH exhibits an impressively low onset potential of 1.305 V vs reversible hydrogen electrode (RHE) and requires only a small potential of 1.34 V vs RHE to deliver a current density of 100 mA cm-2 in 1.0 M KOH + 0.33 M urea. In addition, the NiMnOOH catalyst possesses good long-term working stability.
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