傅里叶变换红外光谱
材料科学
结晶
陶瓷
铋
铒
分析化学(期刊)
矿物学
光谱学
玻璃陶瓷
兴奋剂
化学工程
复合材料
冶金
化学
光电子学
工程类
物理
量子力学
色谱法
作者
Maria Boşca,Lidia Pop,Gheorghe Borodi,Petru Pășcuța,E. Culea
标识
DOI:10.1016/j.jallcom.2009.01.001
摘要
Glasses with the xEr2O3(100 − x)[72Bi2O3·25PbO·3Ag2O] composition where x = 0–20 mol% were prepared and later thermally treated. The local environments characteristic of this system were investigated using X-ray diffraction and FTIR spectroscopy. The results show that the glass or glass ceramic network structure resembles to that of the host matrix, being composed of [BiO3], [BiO6], [PbO3] and [PbO4] structural units. The addition of Er2O3 stabilizes the host glass or glass ceramic structure. The erbium ions play the role of a network modifier in the studied glasses. It was shown that the heat treatment at 650 °C leads to the crystallization of the Bi2O3 and PbO1.44 phases.
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