分流器
材料科学
钨
等离子体
扩散
热扩散率
纳米尺度
聚变能
无定形固体
溅射
表面扩散
分析化学(期刊)
纳米技术
薄膜
热力学
托卡马克
结晶学
物理化学
化学
冶金
物理
吸附
量子力学
色谱法
作者
M.J. Baldwin,R. Doerner
出处
期刊:Nuclear Fusion
[IOP Publishing]
日期:2008-01-23
卷期号:48 (3): 035001-035001
被引量:494
标识
DOI:10.1088/0029-5515/48/3/035001
摘要
Polished W discs exposed to pure He plasma in the PISCES-B linear-divertor-plasma simulator at 1120 and 1320 K are found to develop deeply nanostructured surface layers consisting of a conglomerate of amorphous ‘nanorods’. The growth of the thickness of the nanostructured layer is explored for exposure times spanning 300–(2.2 × 10 4 ) s in He plasmas of density n e ∼ 4 × 10 18 m −3 and temperature T e ∼ 6–8 eV where the average He-ion surface-impact energy is ∼60 eV, below the threshold for physical sputtering. A nanostructured layer in excess of 5 µm thick is observed for the longest exposure time explored. The kinetics of the layer growth are found to follow Fick's law, characterized by an effective diffusive mechanism with coefficients of diffusion: D 1120 K = 6.6 ± 0.4 × 10 −12 cm 2 s −1 and D 1320 K = 2.0± 0.5 × 10 −11 cm 2 s −1 . The diffusion of He atoms in W is considered too rapid to explain the observed growth of surface modification and points to the interplay of other mechanisms, such as the availability of thermal vacancies and/or the slower diffusion of He through the forming nanostructured layer.
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