共聚物
硅氧烷
倍半硅氧烷
材料科学
高分子化学
聚酰亚胺
酰亚胺
纳米复合材料
化学工程
聚合物
复合材料
图层(电子)
工程类
作者
Yue Guan,Yue Sun,Dejing Shang
标识
DOI:10.1080/10601325.2022.2026785
摘要
Spacecrafts circling in low earth orbit suffer from highly reactive atomic oxygen (AO). To shield AO from erosion, a series of polyimide (PI) copolymer containing α,ω'-Aminopropyl poly(dimethyl siloxane)PDMS(Mn = 860 g mol−1), Octa(aminophenyl) silsesquioxanes (OAPS) were successful prepared by a two-step copolymerization. By controlling the amount of dianhydride, the different chain length block dianhydride capped poly (amic acid siloxane) (PAAS) was obtained. Then, the PAAS was reacted with OAPS which contains polyhedral oligomeric silsesquioxane (POSS) and surrounds eight amine groups to give the copolymers film with heat imidization. The effects of the different chain length block of the copolymers on the morphology and structure were investigated using field emission scanning electron microscopy (SEM) and FTIR, respectively. DSC, DMA, TGA and TMA were using to determine the thermal properties of the copolymer films. A poly(imide siloxane) copolymer with POSS nanocomposites show the best atomic oxygen (AO) resistance with the lowest erosion yield of 0.37 × 10−24 cm3 atoms−1. The results indicate that the copolymer films are capable of providing protection against atomic oxygen (AO) attack and may find wide usage in aerospace.
科研通智能强力驱动
Strongly Powered by AbleSci AI