电解质
阳极
原位
锌
电流密度
电化学
化学工程
材料科学
电极
图层(电子)
阻挡层
枝晶(数学)
化学
纳米技术
有机化学
物理化学
冶金
工程类
物理
几何学
数学
量子力学
作者
Peiwen Xu,Minghou Xu,Jie Zhang,Jiabin Zou,Yue Shi,Dan Luo,Dongdong Wang,Haozhen Dou,Zhongwei Chen
标识
DOI:10.1002/anie.202407909
摘要
In‐situ construction of solid electrolyte interfaces (SEI) is an effective strategy to enhance the reversibility of zinc (Zn) anodes. However, in‐situ SEI to afford high reversibility under high current density conditions (≥ 20 mA cm−2) is highly desired yet extremely challenging. Herein, we propose a dual reaction strategy of spontaneous electrostatic reaction and electrochemical decomposition for the in‐situ construction of SEI, which is composed of organic‐rich upper layer and inorganic‐rich inner layer. Particularly, in‐situ SEI performs as “growth binder" at small current density and “orientation regulator” at high current density, which significantly suppresses side reactions and dendrite growth. The in‐situ SEI affords the record‐breaking reversibility of Zn anode under practical conditions, Zn//Zn symmetric cells can stably cycle for over 1300 h and 400 h at current densities of 50 mA cm−2 and 100 mA cm−2, respectively, showcasing an exceptional cumulative capacity of 67.5 Ah cm−2. Furthermore, the practicality of this in‐situ SEI is verified in Zn//PANI pouch cells with high mass loading of 25.48 mg cm−2. This work provides a universal strategy to design advanced SEI for practical Zn‐ion batteries.
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