Direct synthesis of nanosized CHA zeolite free of organic template by a combination of cations as structure directing agents

There is an increasing demand for porous materials able to separate the components of natural gas, mainly CH4 and CO2. Flexible small pore zeolites are interesting candidates due to their high sorption capacity and ability to selectively separate molecules of similar sizes. This selectivity comes from their small pores, large cavities, and pore shapes which can be controlled by the introduction of different extra-framework cations such as Na+, K+, Cs+. Furthermore, the extra-framework cations selectively provide access to the pores and cages of the zeolite depending on the nature of the molecules present. The strategy to prepare CHA-type zeolites across a range of particle sizes, from micron-sized dimensions to nanocrystals with a size of 50 nm, was investigated. The quantities of extra-framework cations and the hydrothermal conditions were optimised in order to avoid the formation of secondary structural phases and selectively target the CHA phase. The CHA-type zeolites were characterised by electron microscopy, elemental analysis, MAS NMR and FTIR spectroscopy, and PXRD. The Si/Al ratio of the obtained CHA zeolite was between 1.7 and 2.6 which is ideal for gas separation applications. The nanosized as-synthesised CHA zeolite (Si/Al = 2.4) demonstrates a high CO2 storage capacity (4.6 mmol/g) making it an ideal candidate for gas separation applications.