过电位
塔菲尔方程
氢氧化钾
材料科学
析氧
氢氧化物
电化学
电极
合金
化学工程
电导率
电流密度
冶金
无机化学
化学
物理化学
工程类
物理
量子力学
作者
Namachivayam Karthik,Raji Atchudan,Thomas Nesakumar Jebakumar Immanuel Edison,Seung Tae Choi
标识
DOI:10.1016/j.matlet.2022.133557
摘要
Stainless steel, a cost-effective Fe, Ni, and Cr alloy, is a promising electrode material for green electrochemical energy conversion systems. Accordingly, this study investigated the effect of potassium hydroxide concentration (KOH; 0.1, 1.0, and 6.0 M) on the oxygen evolution reaction (OER) activity of pristine stainless-steel mesh (pre-SSM) used for the different concentrations denoted by SSM-0.1, SSM-1.0, and SSM-6.0). In particular, SSM-6.0 showed satisfactory OER activity with a low overpotential of 223 mV, and a Tafel slope of 44 mV dec-1 was required to achieve a current density of 10 mA cm−2. This remarkable performance of the electrode resulted from the 6.0 M KOH solution having a considerably higher theoretical specific conductivity (0.6266 S cm−1) than the 1.0 M (0.2153 S cm−1) and 0.1 M (0.0241 S cm−1) KOH solutions.
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