Surface Texture Design of FBR-ALD Pt/C Catalyst to Enhance PEMFC Performance

Proton exchange membrane fuel cell (PEMFC) is an efficient electrochemical energy conversion device that directly generates electricity from the chemical energy of fuels without the emission of greenhouse gases. The most reliable catalyst in PEMFC is Platinum (Pt) metal nanoparticles (NPs) that exhibit excellent electrochemical activity and stability compared to other catalysts. However, using of Pt catalyst is limited due to its very high cost and low abundance on Earth. Therefore, it is important to use Pt catalyst efficiently for making the PEMFC economically viable. In this regard, several synthesis techniques have been developed to reduce the loading and uniform distribution of Pt NPs on carbon support with high electrochemically active surface area (ECSA). One of the most efficient techniques to uniformly deposit Pt NPs with a controllable size on carbon support is to use a fluidized bed reactor (FBR) atomic layer deposition (ALD). Our group recently demonstrated that FBR-ALD Pt/C catalysts can exhibit high fuel cell performance and high endurance even with low Pt NPs loading by optimizing the surface of carbon supports combined with proper ALD process parameters [1]. However, it is still challenging to further improve the fuel cell performance by rational designing the Pt NPs surfaces in order to make FBR-ALD into a viable commercial production. In this study, a unique way to improve the fuel cell performance was suggested to design and optimize atomic scale surface textures of Pt NPs. During the FBR-ALD of Pt NPs, in-situ surface modulation of Pt NPs was applied via a proper protective oxide deposition and etching. A careful surface studies was performed to analyze the surface morphology, distribution and uniformity of Pt NPs. Electrochemical performances were evaluated and optimized by measuring cyclic voltammetry (CV) and oxygen reduction reaction (ORR). Finally, a fuel cell performance was studied through membrane electrode assembly (MEA) characteristics. References W. J. Lee, S. Bera, H. C. Shin, W. P. Hong, S. J. Oh, Z. wan, S. H. Kwon, Adv. Mater. Interfaces 6, 1901210 (2019).