Cross-Linked Anion-Exchange Membranes with Dipole-Containing Cross-Linkers Based on Poly(terphenyl isatin piperidinium) Copolymers

To balance the ionic conductivity and dimensional stability of anion-exchange membranes (AEMs), several cross-linked ether-free poly(terphenyl isatin piperidinium) copolymers were synthesized using 1,2-bis(2-aminoethoxy)ethane as a cross-linker. By introducing an alkyl diamine-based hydrophobic cross-linker as a control, the effects of the dipolar-molecule-containing cross-linker on the comprehensive performance of the membranes were investigated. Cation-dipole interactions between the cations and the hydrophilic ethylene oxide cross-linker enhance the self-assembly capability of the cationic groups. The introduction of the rotatable ethylene oxide cross-linker facilitates the flexibility of the cross-linked networks, thereby promoting hydrophilic/hydrophobic phase separation and inhibiting excessive swelling of the corresponding AEMs simultaneously. The resulting PTPBHIN-O₁₉ membrane showed a high hydroxide conductivity (151.69 mS cm^-1) and low swelling ratio (10.53%) at 80 °C. Furthermore, owing to the cross-linked structure and ether-free polymer backbone with high alkali resistance, the membranes treated in 3 M NaOH at 80 °C for 1600 h maintained ≥85% of their hydroxide conductivity, indicating excellent alkaline stability. A H₂/O₂ fuel cell based on the PTPBHIN-O₁₉ AEM exhibited a maximum power density of 398 mW cm^-2 at 515 mA cm^-2.