Broad‐Range‐Response Battery‐Type All‐in‐one Self‐Powered Stretchable Pressure‐Sensitive Electronic Skin

Abstract Highly sensitive self‐powered stretchable electronic skins with the capability of detecting broad‐range dynamic and static pressures are urgently needed with the increasing demands for miniaturized wearable electronics, robots, artificial intelligence, etc. However, it remains a great challenge to achieve this kind of electronic skins. Here, unprecedented battery‐type all‐in‐one self‐powered stretchable electronic skins with a novel structure composed of pressure‐sensitive elastic vanadium pentoxide (V 2 O 5 ) nanowire‐based porous cathode, elastic porous polyurethane /carbon nanotube/polypyrrole anode, and polyacrylamide ionic gel electrolyte are reported. A new battery‐type self‐powered pressure sensing mechanism involving the output current variation caused by the resistance variation of the electrodes and electrolytes under external pressure is revealed. The battery‐type self‐powered electronic skins combining high sensitivity, broad response range (1.8 Pa–1.5 MPa), high fatigue resistance, and excellent stability against stretching (50% tensile strain) are achieved for the first time. This work provides a new and versatile battery‐type sensing strategy for the design of next‐generation all‐in‐one self‐powered miniaturized sensors and electronic skins.