碳酰肼
敏化
色素敏化染料
发色团
金属
化学
光化学
材料科学
纳米技术
医学
有机化学
物理化学
免疫学
电极
电解质
作者
Ali Hamzah Alessa,Sara A. Alqarni,Jihan Qurban,Hawra A. Alghasham,Gadeer R.S. Ashour,Abrar Bayazeed,Arwa Alharbi,Nashwa M. El‐Metwaly
标识
DOI:10.1016/j.molliq.2024.125354
摘要
Dye-sensitized solar cells (DSSCs) have emerged as a promising alternative to traditional silicon-based photovoltaic devices due to their low-cost fabrication and tunable optical properties. One effective strategy to improve the light-harvesting capabilities of DSSCs is co-sensitization, which involves combining multiple dyes with complementary absorption properties. In this study, we report the co-sensitization of carbohydrazide-based organic chromophores, namely MRK-1–2, with a benchmark metal-complex dye (black dye) to enhance the photovoltaic performance of DSSCs. The synthesis of MRK-1–2 sensitizers is described, and their photophysical properties are thoroughly analyzed. The absorption spectra of the co-sensitizers revealed distinct absorption bands associated with intramolecular charge transfer and localized aromatic π-π* transitions. Sensitization by MRK-1–2 resulted in photovoltaic efficiencies ranging between 5.02–5.88 %. The ternary co-sensitization system of carbohydrazide-based chromophores (MRK-1–2 + black dye) showed promising potential for enhancing the short-circuit current density (JSC) (20.32–21.45 mA/cm2), open-circuit voltage VOC (691–729 mV), and overall power conversion efficiency (PCE) (9.52–9.90 %). This significant improvement in photovoltaic performance is attributed to the complementary light-harvesting abilities of the co-sensitizers, leading to enhanced light absorption and efficient charge separation and injection processes. The superior performance, with a (PCE) of up to 9.90 %, can be attributed to complementary light absorption, efficient charge injection facilitated by the carboxylic acid moiety in MRK-2, and suppressed charge recombination within the co-sensitized system. The findings of this study will contribute to the advancement of DSSC technologies and bring us closer to sustainable and renewable energy solutions.
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