Photocatalytic Degradation of Tetracycline by Supramolecular Materials Constructed with Organic Cations and Silver Iodide

Photocatalytic degradation, as a very significant advanced oxidation technology in the field of environmental purification, has attracted extensive attention in recent years. The design and synthesis of catalysts with high-intensity photocatalytic properties have been the focus of many researchers in recent years. In this contribution, two new supramolecular materials {[(L1)·(Ag4I7)]CH3CN} (1), {[(L2)·(Ag4I7)]CH3CN} (2) were synthesized by solution volatilization reaction of two cationic templates 1,3,5-Tris(4-aminopyridinylmethyl)-2,4,6-Trimethylphenyl bromide (L1) and 1,3,5-Tris(4-methyl pyridinyl methyl)-2,4,6-trimethylphenyl bromide (L2) with metal salt AgI at room temperature, respectively. The degradation effect of 1 and 2 as catalyst on tetracycline (TC) under visible light irradiation was studied. The results showed that the degradation of TC by 1 was better than that by 2 and both of them had good stability and cyclability. The effects of pH value, catalyst dosage, and anion in water on the photocatalytic performance were also investigated. The adsorption kinetics fit the quasi-first-order model best. After 180 min of irradiation with 1, the degradation rate of TC can reach 97.91%. In addition, the trapping experiments showed that ·OH was the main active substance in the photocatalytic degradation of TC compared with ·O2− and h+. Because of its simple synthesis and high removal efficiency, catalyst 1 has potential value for the treatment of wastewater containing organic matter.