四苯乙烯
光致变色
水溶液
聚集诱导发射
荧光
两亲性
猝灭(荧光)
自组装
材料科学
纳米颗粒
胶束
化学
超分子化学
墨水池
尼罗河红
光化学
紧身衣
胶体
化学工程
纳米技术
有机化学
共聚物
聚合物
物理
量子力学
作者
Qian Xu,Ziyu Qin,Ning Wang,Shengyu Feng,Xing‐Dong Xu
标识
DOI:10.1016/j.dyepig.2021.109479
摘要
Since the discovery of aggregation induced emission (AIE) phenomenon, various stimuli-responsive materials have been rapidly developed. However, the development of self-assembled amphiphilic light-responsive materials in aqueous solution needs to be solved urgently. In this work, three new amphiphilic tetraphenylethylene (TPE) derivatives (TPE-1, TPE-2 and TPE-3) with AIE properties and photochromism were synthesized and investigated. Owing to the different electron-donating abilities of the three groups attached to TPE units, the TPE-1, TPE-2 and TPE-3 displayed blue-green, yellow-green, and orange fluorescence emission in the aggregation state respectively. Furthermore, ordered nanoparticles formed via self-assembly in aqueous solution showed interesting photocyclization behaviors, which lead to fluorescence quenching under ultraviolet light irradiation (λ = 365 nm). Therefore, the compounds can be used as anti-counterfeiting ink in the information encryption due to their amphiphilicity and photo-responsiveness. This work contributes new members to the amphiphilic light-responsive materials family and demonstrates the potential for applications in the fields of optical information storage, information security protection, and erase/rewrite systems.
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