材料科学
易燃液体
电解质
锂(药物)
阳极
阴极
化学工程
磷酸三甲酯
阻燃剂
金属
电导率
阴极保护
电化学
复合材料
电极
金属锂
磷酸盐
冶金
废物管理
有机化学
电气工程
医学
化学
物理化学
工程类
内分泌学
作者
Shuang‐Jie Tan,Junpei Yue,Yufei Tian,Qiang Ma,Jing Wan,Yao Xiao,Juan Zhang,Ya‐Xia Yin,Rui Wen,Sen Xin,Yu‐Guo Guo
标识
DOI:10.1016/j.ensm.2021.04.020
摘要
Solid-liquid hybrid electrolytes (SLHEs) are promising electrolyte candidates for Li-metal batteries. However, most of the components of SLHE are flammable, posing safety risks. Here, a non-flammable SLHE was proposed by in-situ encapsulating a flame-retardant liquid phosphate into a robust solid polycarbonate matrix. The in-situ solidified SLHE simultaneously features high Li+ conductivity (4.4 mS cm−1), Young's modulus (12.4 GPa), Li+ transference number (0.76) and a wide electrochemical window (0-4.9 V vs. Li+/Li), which help to effectively suppress dendrites and unfavorable side reactions at the anode and provide compatibility with the high-voltage cathode. By employing non-flammable SLHE, a prototype Li||LiNi0.8Co0.1Mn0.1O2 cell retains 87.7% of the initial capacity after 200 cycles, and the Ah level Li||LiNi0.8Co0.1Mn0.1O2 pouch cells showed enhanced safety by passing the nail test by authorized third parties. This study inspires the optimal design of SLHEs towards practical realization of safe and stable Li-metal batteries.
科研通智能强力驱动
Strongly Powered by AbleSci AI