化学
过氧化氢
催化作用
氢氧化物
吸光度
检出限
自来水
齿合度
无机化学
校准曲线
分解
腐植酸
分光光度法
核化学
金属
色谱法
有机化学
工程类
环境工程
肥料
作者
Susumu Kawakubo,Yuki Hagihara,Yukiko Honda,Masaaki Iwatsuki
标识
DOI:10.1016/s0003-2670(99)00076-8
摘要
A new sensitive catalytic method for the determination of labile iron has been developed using iron-catalyzed oxidation of o-phenylenediamine (OPDA) with hydrogen peroxide at pH 4.5 and 40°C. Absorbance (A) of the oxidized OPDA was monitored at 450 nm for a reaction time (t) of 10 min. The calibration graph was constructed by using ΔA/Δt. The same calibration graph with a linear range of 0–20 μg l−1 was obtained for Fe(II) and Fe(III). The detection limit was 0.06 μg l−1. Labile form of iron was characterized by the kinetic and complexation studies for the speciation of iron. The results suggested that Fe(II) was oxidized to Fe(III) at the initial reaction step and Fe3+ and FeIIILi, where i = 1 or 2 for a unidendate and i = 1 for a bidentate ligand (L), were determined as the labile iron. Non-labile Fe(III) hydroxide changed to a labile form by the complexation with humic acid. By the combined use of acid decomposition, the proposed method was successfully applied to the determination of soluble labile and non-labile iron in river and tap water samples.
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