Substrate Size‐Selective Catalysis with Zeolite‐Encapsulated Gold Nanoparticles

Angewandte Chemie International EditionVolume 49, Issue 20 p. 3504-3507 Communication Substrate Size-Selective Catalysis with Zeolite-Encapsulated Gold Nanoparticles† Anders B. Laursen, Anders B. Laursen Haldor Topsøe A/S, Nymøllevej 55, 2800 Kgs. Lyngby (Denmark) DTU Chemical Engineering, Technical University of Denmark, 2800 Kgs. Lyngby (Denmark)Search for more papers by this authorKaren T. Højholt, Karen T. Højholt Haldor Topsøe A/S, Nymøllevej 55, 2800 Kgs. Lyngby (Denmark) Center for Sustainable and Green Chemistry, Technical University of Denmark, 2800 Kgs. Lyngby (Denmark)Search for more papers by this authorLars F. Lundegaard, Lars F. Lundegaard Haldor Topsøe A/S, Nymøllevej 55, 2800 Kgs. Lyngby (Denmark)Search for more papers by this authorSøren B. Simonsen, Søren B. Simonsen Haldor Topsøe A/S, Nymøllevej 55, 2800 Kgs. Lyngby (Denmark)Search for more papers by this authorStig Helveg, Stig Helveg Haldor Topsøe A/S, Nymøllevej 55, 2800 Kgs. Lyngby (Denmark)Search for more papers by this authorFerdi Schüth Prof. Dr., Ferdi Schüth Prof. Dr. Max-Planck-Institut für Kohlenforschung, 45470 Mülheim (Germany)Search for more papers by this authorMichael Paul, Michael Paul Max-Planck-Institut für Kohlenforschung, 45470 Mülheim (Germany)Search for more papers by this authorJan-Dierk Grunwaldt Prof., Jan-Dierk Grunwaldt Prof. DTU Chemical Engineering, Technical University of Denmark, 2800 Kgs. Lyngby (Denmark)Search for more papers by this authorSøren Kegnæs, Søren Kegnæs Center for Sustainable and Green Chemistry, Technical University of Denmark, 2800 Kgs. Lyngby (Denmark)Search for more papers by this authorClaus H. Christensen Prof., Claus H. Christensen Prof. chc@topsoe.dk Haldor Topsøe A/S, Nymøllevej 55, 2800 Kgs. Lyngby (Denmark) Center for Sustainable and Green Chemistry, Technical University of Denmark, 2800 Kgs. Lyngby (Denmark)Search for more papers by this authorKresten Egeblad, Kresten Egeblad kreg@topsoe.dk Haldor Topsøe A/S, Nymøllevej 55, 2800 Kgs. Lyngby (Denmark) Center for Sustainable and Green Chemistry, Technical University of Denmark, 2800 Kgs. Lyngby (Denmark)Search for more papers by this author Anders B. Laursen, Anders B. Laursen Haldor Topsøe A/S, Nymøllevej 55, 2800 Kgs. Lyngby (Denmark) DTU Chemical Engineering, Technical University of Denmark, 2800 Kgs. Lyngby (Denmark)Search for more papers by this authorKaren T. Højholt, Karen T. Højholt Haldor Topsøe A/S, Nymøllevej 55, 2800 Kgs. Lyngby (Denmark) Center for Sustainable and Green Chemistry, Technical University of Denmark, 2800 Kgs. Lyngby (Denmark)Search for more papers by this authorLars F. Lundegaard, Lars F. Lundegaard Haldor Topsøe A/S, Nymøllevej 55, 2800 Kgs. Lyngby (Denmark)Search for more papers by this authorSøren B. Simonsen, Søren B. Simonsen Haldor Topsøe A/S, Nymøllevej 55, 2800 Kgs. Lyngby (Denmark)Search for more papers by this authorStig Helveg, Stig Helveg Haldor Topsøe A/S, Nymøllevej 55, 2800 Kgs. Lyngby (Denmark)Search for more papers by this authorFerdi Schüth Prof. Dr., Ferdi Schüth Prof. Dr. Max-Planck-Institut für Kohlenforschung, 45470 Mülheim (Germany)Search for more papers by this authorMichael Paul, Michael Paul Max-Planck-Institut für Kohlenforschung, 45470 Mülheim (Germany)Search for more papers by this authorJan-Dierk Grunwaldt Prof., Jan-Dierk Grunwaldt Prof. DTU Chemical Engineering, Technical University of Denmark, 2800 Kgs. Lyngby (Denmark)Search for more papers by this authorSøren Kegnæs, Søren Kegnæs Center for Sustainable and Green Chemistry, Technical University of Denmark, 2800 Kgs. Lyngby (Denmark)Search for more papers by this authorClaus H. Christensen Prof., Claus H. Christensen Prof. chc@topsoe.dk Haldor Topsøe A/S, Nymøllevej 55, 2800 Kgs. Lyngby (Denmark) Center for Sustainable and Green Chemistry, Technical University of Denmark, 2800 Kgs. Lyngby (Denmark)Search for more papers by this authorKresten Egeblad, Kresten Egeblad kreg@topsoe.dk Haldor Topsøe A/S, Nymøllevej 55, 2800 Kgs. Lyngby (Denmark) Center for Sustainable and Green Chemistry, Technical University of Denmark, 2800 Kgs. Lyngby (Denmark)Search for more papers by this author First published: 28 April 2010 https://doi.org/10.1002/anie.200906977Citations: 155 † We gratefully acknowledge the participation of the CTCI Foundation, Taiwan, in the establishment of the in situ electron microscopy facility at Haldor Topsøe A/S and the Catalysis for Sustainable Energy Initiative, Technical University of Denmark. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Graphical Abstract The Dark Crystal: A hybrid material is reported that is comprised of 1–2 nm sized gold nanoparticles, accessible only through zeolite micropores in a silicalite-1 crystal, as shown by three-dimensional TEM tomography (see picture). Calcination experiments indicate that the embedded nanoparticles are highly stable towards sintering. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_200906977_sm_insitu.avi3.2 MB insitu anie_200906977_sm_miscellaneous_information.pdf45.3 KB miscellaneous_information anie_200906977_sm_tilt.mpg19.4 MB tilt anie_200906977_sm_tomo.mpg36.1 MB tomo Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume49, Issue20May 3, 2010Pages 3504-3507 RelatedInformation