气凝胶
材料科学
液晶
单体
聚合
化学工程
反射损耗
扩散
反射(计算机编程)
聚合物
高分子化学
光电子学
复合数
复合材料
物理
程序设计语言
工程类
热力学
计算机科学
作者
Qi Chen,Dong Wang,Hong Gao,Jingjing Zhang,Yan Xing,Zhou Yang,Hui Cao,Wanli He
标识
DOI:10.1080/02678292.2018.1542747
摘要
In the study, a novel method of broadening the bandwidth by fabricating the silica aerogel film composited with the chiral nematic liquid crystal (N*-LC) is proposed. Diffusion of chiral compound filled in the silica aerogel resulted in the non-uniform pitch distribution, which can be anchored by UV-radical polymerisation. The results strongly suggested that the reflection bandwidth could be broadened preferably by adjusting the silica aerogel condensation time, the content of UV polymerisable free radical monomer and the polymerisation temperature. The reflection bandwidth was broadened from 270 nm to 878 nm, and the centre wavelength was blue-shifted by 642 nm. A general correlation among the silica aerogel condensation time, the polymerisation condition, and the reflective region will be outlined.
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