化学
分子间力
催化作用
钯
计算化学
药物化学
有机化学
分子
作者
Wentao Zhao,Fang Gao,Dongbing Zhao
标识
DOI:10.1002/anie.201803156
摘要
Abstract Described herein is the first intermolecular σ‐bond exchange reaction between the C−C bond of cyclopropenones and C−Si bond of (benzo)silacyclobutanes and it proceeds smoothly by treatment with either 1 mol % of a palladium or 2 mol % of a nickel catalyst. This reaction constitutes an unprecedented route for the synthesis of various sila(benzo)suberones. And it is also the first example of a σ‐bond exchange reaction involving cyclopropenones.
科研通智能强力驱动
Strongly Powered by AbleSci AI