Working principle of carrier selective poly-Si/c-Si junctions: Is tunnelling the whole story?

量子隧道 钝化 氧化物 共发射极 透射电子显微镜 等效串联电阻 材料科学 光电子学 电子 热的 图层(电子) 凝聚态物理 纳米技术 物理 电气工程 电压 热力学 工程类 冶金 量子力学
作者
Robby Peibst,Udo Römer,Yevgeniya Larionova,Michael Rienäcker,Agnes Merkle,Nils Folchert,Sina Reiter,M. Turcu,Byungsul Min,Jan Krügener,Dominic Tetzlaff,E. Bugiel,Tobias Wietler,Rolf Brendel
出处
期刊:Solar Energy Materials and Solar Cells [Elsevier BV]
卷期号:158: 60-67 被引量:198
标识
DOI:10.1016/j.solmat.2016.05.045
摘要

We present arguments that additional effects besides laterally homogenous tunnelling might occur in carrier-selective poly-Si/c-Si junctions: (i) the symmetrical electrical behaviour of n+ and p+ poly-Si/c-Si junctions, (ii) direct observation of structural modifications of the interfacial oxide upon thermal treatment by transmission electron microscopy, even for poly-Si/c-Si junctions with good passivation quality, and (iii) the achievement of low junction resistances even for interfacial oxide thicknesses >2 nm after thermal treatment. We present an alternative picture, essentially based on a localized current flow through the interfacial oxide, mediated either by local reduction of the oxide layer thickness or by pinholes. In consequence, the local current flow implies transport limitations for both minority and majority carriers in the c-Si absorber, and thus a correlation between recombination current and series resistance. Thus, a poly-Si/c-Si junction can also be explained within the framework of a classical pn junction picture for a passivated, locally contacted emitter, e.g. by the model of Fischer. Both electron selective contacts (n+ poly-Si) and hole selective contacts (p+ poly-Si) can be described consistently when using reasonable input parameters. Especially for p+ poly-Si/c-Si junctions, our model could guideline further improvement.
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