氰化
化学
溶剂
甲烷氧化偶联
金属
苯醌
药物化学
有机化学
催化作用
作者
Shanshan Kong,Lingqiong Zhang,Xiaoli Dai,Lianzhi Tao,Chunsong Xie,Lei Shi,Min Wang
标识
DOI：10.1002/adsc.201500096
摘要
Abstract A direct cyanation of benzyl ethers and 1,3‐diarylpropenes with TMSCN was performed under solvent‐ and metal‐free conditions. This oxidative cross dehydrative coupling (CDC) reaction was promoted by 2,3‐dichloro‐5,6‐dicyano‐1,4‐benzoquinone (DDQ) and provided rapid access to a broad range of nitriles in good to excellent yields. magnified image
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