Power Generation from Moisture Fluctuations Using Polyvinyl Alcohol‐Wrapped Dopamine/Polyvinylidene Difluoride Nanofibers

Abstract Despite the boom in the water‐triggered electric power generation technologies, few attempts have been made with a broader horizonyielding the electricity from sweat, which is of great value for low‐power‐consumption wearable electronics. Here, an electromechanical coupling and humidity‐actuated two‐in‐one humidity actuator‐driven piezoelectric generator (HAPG) are reported, that can yield continuous electric power from fluctuations in the ambient humidity. It is composed of polyvinyl alcohol (PVA)‐wrapped highly aligned dopamine (DA)/polyvinylidene fluoride (PVDF) shell/core nanofibers (PVA@DA/PVDF NFs). As‐received PVA@DA/PVDF NFs can exchange water with the ambient humidity to perform expansion and contraction and convert them into electric power. An all‐fiber‐based portable HAPG is fabricated and tested on human palm skin. The devices show high sensitivity and accuracy for converting the mental sweating‐derived continuous moisture fluctuations into electric power. This electric power can be stored in capacitors, which is expected to power micro‐ and nano‐electronic devices or be used in electrotherapy such as electrical stimulation to promote wound healing. Beyond this, the obtained voltage profiles exhibit unique features that can reflect the typical sweat damping oscillation curve features.