光降解
材料科学
光催化
X射线光电子能谱
可见光谱
多孔性
比表面积
金属有机骨架
打赌理论
降级(电信)
复合材料
化学工程
光电子学
催化作用
化学
计算机科学
有机化学
吸附
工程类
电信
作者
Panbing Hu,Congfei Yao,Lin Yang,Yanmei Xin,Yuqing Miao
标识
DOI:10.1016/j.colsurfa.2021.127248
摘要
Metal-organic frameworks (MOFs) have attracted great interest in the field of photocatalysis because of their adjustable porous structure and semiconductor properties. In this research, a new type of MIL-88B(Fe)/Bi2WO6 was successfully prepared by growing MIL-88B(Fe) on the surface of flower-like Bi2WO6 spheres. The structures of materials were characterized through XRD, BET, XPS, SEM, TEM, EDX and FT-IR. 7-MIL-88B(Fe)/Bi2WO6 exhibits the highest photocatalytic performance with a degradation rate of 96.4% within 90 min under visible light irradiation. Compared with pure Bi2WO6 or MIL-88B(Fe), 7-MIL-88B(Fe)/Bi2WO6 exhibits the largest specific surface area to provide more active sites. Additionally, the ·O2- and ·OH played dominant roles during the photocatalytic degradation process based on trapping and ESR tests. Through cyclic experiments, MIL-88B(Fe)/Bi2WO6 composites show good stability and degradation efficiency, indicating its application potential in the environmental field.
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