岩石圈
热传导
电导率
克拉通
电阻率和电导率
凝聚态物理
材料科学
质子
导电体
钻石
离子键合
离子
化学
地质学
复合材料
电气工程
物理
工程类
物理化学
古生物学
有机化学
构造学
量子力学
作者
Junkai Zhang,Jianguo Du,Yanzhang Ma
标识
DOI:10.1002/essoar.10506472.1
摘要
The electrical transport behavior of lizardite was investigated by in-situ impedance measurements up to 22.6 GPa in a diamond anvil cell with comparation to its dehydrated counterpart. The conductivity of lizardite is found to increase one order of magnitude with increasing pressures from 0.2 to 1.9 GPa, due to pressure-activated ionic and electronic transportation. The proton hopping and hopping-created vacancy accounts for the conduction mechanisms. Compression initially promotes proton hopping at lower pressures and then impedes it at elevates pressure to make conduction purely electronic. Compared to the dehydrated specimen, the hydroxyl in lizardite enhances conductivity 4-7 times. The electronic resistivity at higher pressures gradually increases at a constant rate, except in the pressure range where pressure minimized the misfit structural disordering. The pressure-activated proton hopping in the lizardite and other phyllosilicates may ascribe the high conductive layer in the craton lithosphere and geoelectric anomalies related to earthquakes.
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