The results of experimental study on intergranular corrosion of sensitized 316L stainless steel by mass loss measurement and metallographic inspection method through boiling nitric acid experiments show that: the intergranular corrosion behavior of sensitized 316L stainless steel is mainly divided into three stages: initiation stage, stable stage and rapid development stage, the corrosion rate added with the experimental time extension; the degree of intergranular corrosion has a direct relationship with material grain size, large grain regions have a small degree of intergranular corrosion; and small grain regions have a large degree of intergranular corrosion, even leading to pitting corrosion.