物理
范德瓦尔斯力
直线(几何图形)
不对称
原子物理学
量子力学
分子
几何学
数学
作者
M. V. Romalis,E. Miron,G. D. Cates
出处
期刊:Physical Review A
[American Physical Society]
日期:1997-12-01
卷期号:56 (6): 4569-4578
被引量:185
标识
DOI:10.1103/physreva.56.4569
摘要
We studied the line shape of Rb ${D}_{1}$ and ${D}_{2}$ resonance lines in the presence of 1--10 amg of several gases: ${}^{3}$He, ${}^{4}$He, N${}_{2}$, and Xe. We found that the line cores are well described by the asymmetric line shape expected for a van der Waals interatomic potential. The width and shift of the lines is proportional to the density of the foreign gas with high degree of accuracy, while the asymmetry is independent of the density. The constants of proportionality for pressure broadening and shift were measured with much higher accuracy than in previous experiments. We also studied the density dependence of the oscillator strength of the transitions.
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