互变异构体
席夫碱
价(化学)
锰
材料科学
高分子化学
立体化学
化学
有机化学
冶金
作者
Daniel Ruiz‐Molina,Klaus Wurst,D. N. Hendrickson,Concepció Rovira,Jaume Veciana
标识
DOI:10.1002/1616-3028(20020517)12:5<347::aid-adfm347>3.0.co;2-t
摘要
The synthesis, characterization, and X-ray structure of new manganese valence tautomeric complexes are reported here. The feasibility to synthesize, characterize, and study the new tautomeric complexes as stable species allowed us to establish a new switching molecular array of six states that interconvert reversibly either thermally (valence tautomerism) or by a reversible oxidation process.
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