立体化学
真菌
化学
呋喃
海洋真菌
二维核磁共振波谱
绝对构型
植物
生物
有机化学
作者
Qi‐Hui Zhang,Tian Li,Zong-Liang Sun,Shuai Fang,Gong-Li Cai,Yujia Wang,Yue‐Hu Pei
标识
DOI:10.1080/10286020.2015.1009899
摘要
Two new secondary metabolites, (2S)-5-acetamidopentyl-2-hydroxypropanoate (1) and 2, 5, 7-trihydroxy-4-(3′-methylbut-2′-en-1′-yl) oxy-2H-naphtho [1, 8-b c] furan-9-one (2) were isolated from the marine-derived fungus Nigrospora sphaerica. The structures were established on the basis of their spectroscopic data, including 1D NMR and 2D NMR, HR-TOF-MS, and the absolute configuration of compound 1 was determined by the Mosher method.
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